Useful information of Black Goo
Posted: Jul 6th, '06, 12:47
I was poking about and found this article from Down Under. It addresses a lot of questions we are all having about the Black Goo.
Here is the exerpt that applies:
7.2 Deposit Formation
Various studies investigating deposit formation on engines using ethanol-blended fuels have been performed on four-stoke and two-stroke engines. The majority of work on four-stroke engines is of automotive background.
Four-stroke engines may experience intake system deposits (ISD). ISDs are the deposits discussed in any significant detail by the various authors of the literature reviewed. In particular, deposits on the back of the intake valve is referenced as the area of most concern. This concern is clear due to the intake valve and seat area presenting the flow restriction point in the intake tract of modern engines.
Intake system deposits are reported by (13,14) to be more prevalent with fuels containing alcohol. The authors14 explain that gasoline contains two types of additive packages to control deposits. The two different additive packages are formulated to control deposits on the pintle of the fuel injector to ensure accurate fuel metering and to control the deposits on the surfaces of the intake system, particularly the intake valve, to ensure the engines charge airflow is not compromised.
Their detailed testing has shown that adding 10% by volume neat ethanol to gasoline with adequate ISD additive increased intake valve deposits by more than 350%. [ed: this BOLD was added by PETER]
This is not only due to the dilution effect but also due to an antagonistic effect since neat ethanol blended at 10% by volume with gasoline without ISD additive increased intake valve deposits by 37% over the gasoline base without ISD additive. Increasing the ISD additive by 50% over the normal concentration in gasoline was found necessary with 10% ethanol blends in order to achieve the same deposit control as with normal ISD additive levels in gasoline. Some of the experiences reported by (14) are confirmed by (11). Firstly that intake system deposits have been found in the intake valve area, and also includes the intake manifold area; and secondly that the deposits can be controlled with higher additive levels than would be required for gasoline only11.
Crankcase scavenged two-stroke engines may experience detrimental deposits in the piston ring land area as documented by Kasperson and Reynolds28. The piston ring land deposits tended to cause ring stick, where the piston ring becomes stuck in the pistons ring groove. These ring land deposits are common in engines operating on gasoline; solvents and detergents in the fuel and oil control the severity of the deposits.
11 K. Owen and T. Coley, 1990, 'Automotive fuels handbook'
13 J.C. Guibet, 1999, 'Fuels and Engines'
14 Clifford M. Shiblom and Gary A. Schoonveld, 'Effect of Intake Valve Deposits of Ethanol and Additives Common to the Available Ethanol Supply' SAE 902109
Note: "ISD" stands for "Intake System Deposits
If you have more interest here is a link to the whole article:
http://eriss.erin.gov.au/atmosphere/fue ... ility.html
And here is a link to another interesting article that discusses further the problems with ethanol, detergent gas, ISD's and intake valve deposits (IVD's)
The whole article is very informative, but specifically check out chapter 4 page 20
http://64.233.161.104/search?q=cache:aR ... =clnk&cd=4
That last one is in HTML format because it is faster on my old computer that way, but at the top of the article there is a link that will take you to a PDF version if you prefer.
Note how they discuss that the type of engine, the specific arrangement of specific valves, and the way you "drive" all can effect the formation of deposits. Particualrly the post shut down heat soak.
All of this suggests to me that the fiberglass tank may not be the source of the black goo. We also do know that some fiberglass tanks going back as early as the late 1960's are perfectly OK with ethanol. Some underground storage tanks used at gas stations have been tested and certified for continued use with E-10 going back that far. Keep in mind, though, that this doesn't mean that all fiberglass tanks are 100% OK. There still might be issues with some fiberglass resins and ethanol. The question is which ones and how do you know what you have in your boat?
Lastly here is a link that discusses problems with phase separation in a fairly intelligent manner:
http://64.233.161.104/search?q=cache:1o ... lr=lang_en
Note that tis points out that up to 80% of the ethanol can come out of the gas with water and phase separation.
P.S. I am now a fan of the new style bbs. It was a piece of cake to put up these links!
Here is the exerpt that applies:
7.2 Deposit Formation
Various studies investigating deposit formation on engines using ethanol-blended fuels have been performed on four-stoke and two-stroke engines. The majority of work on four-stroke engines is of automotive background.
Four-stroke engines may experience intake system deposits (ISD). ISDs are the deposits discussed in any significant detail by the various authors of the literature reviewed. In particular, deposits on the back of the intake valve is referenced as the area of most concern. This concern is clear due to the intake valve and seat area presenting the flow restriction point in the intake tract of modern engines.
Intake system deposits are reported by (13,14) to be more prevalent with fuels containing alcohol. The authors14 explain that gasoline contains two types of additive packages to control deposits. The two different additive packages are formulated to control deposits on the pintle of the fuel injector to ensure accurate fuel metering and to control the deposits on the surfaces of the intake system, particularly the intake valve, to ensure the engines charge airflow is not compromised.
Their detailed testing has shown that adding 10% by volume neat ethanol to gasoline with adequate ISD additive increased intake valve deposits by more than 350%. [ed: this BOLD was added by PETER]
This is not only due to the dilution effect but also due to an antagonistic effect since neat ethanol blended at 10% by volume with gasoline without ISD additive increased intake valve deposits by 37% over the gasoline base without ISD additive. Increasing the ISD additive by 50% over the normal concentration in gasoline was found necessary with 10% ethanol blends in order to achieve the same deposit control as with normal ISD additive levels in gasoline. Some of the experiences reported by (14) are confirmed by (11). Firstly that intake system deposits have been found in the intake valve area, and also includes the intake manifold area; and secondly that the deposits can be controlled with higher additive levels than would be required for gasoline only11.
Crankcase scavenged two-stroke engines may experience detrimental deposits in the piston ring land area as documented by Kasperson and Reynolds28. The piston ring land deposits tended to cause ring stick, where the piston ring becomes stuck in the pistons ring groove. These ring land deposits are common in engines operating on gasoline; solvents and detergents in the fuel and oil control the severity of the deposits.
11 K. Owen and T. Coley, 1990, 'Automotive fuels handbook'
13 J.C. Guibet, 1999, 'Fuels and Engines'
14 Clifford M. Shiblom and Gary A. Schoonveld, 'Effect of Intake Valve Deposits of Ethanol and Additives Common to the Available Ethanol Supply' SAE 902109
Note: "ISD" stands for "Intake System Deposits
If you have more interest here is a link to the whole article:
http://eriss.erin.gov.au/atmosphere/fue ... ility.html
And here is a link to another interesting article that discusses further the problems with ethanol, detergent gas, ISD's and intake valve deposits (IVD's)
The whole article is very informative, but specifically check out chapter 4 page 20
http://64.233.161.104/search?q=cache:aR ... =clnk&cd=4
That last one is in HTML format because it is faster on my old computer that way, but at the top of the article there is a link that will take you to a PDF version if you prefer.
Note how they discuss that the type of engine, the specific arrangement of specific valves, and the way you "drive" all can effect the formation of deposits. Particualrly the post shut down heat soak.
All of this suggests to me that the fiberglass tank may not be the source of the black goo. We also do know that some fiberglass tanks going back as early as the late 1960's are perfectly OK with ethanol. Some underground storage tanks used at gas stations have been tested and certified for continued use with E-10 going back that far. Keep in mind, though, that this doesn't mean that all fiberglass tanks are 100% OK. There still might be issues with some fiberglass resins and ethanol. The question is which ones and how do you know what you have in your boat?
Lastly here is a link that discusses problems with phase separation in a fairly intelligent manner:
http://64.233.161.104/search?q=cache:1o ... lr=lang_en
Note that tis points out that up to 80% of the ethanol can come out of the gas with water and phase separation.
P.S. I am now a fan of the new style bbs. It was a piece of cake to put up these links!